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Another class of quantum wire can be formed by patterning the substrate before growth. This leads to the formation of so-called V-grooved quantum wires, see e.g. [7], p. 35; the solution of these has been dealt with by Gangopadhyay and Nag [160], and will also be touched upon later in Section 13.4. Quantum dots (see [8] for an introduction to their applications) can again be formed by further lithography and etching, e.g. if a quantum well sample is etched to leave pillars rather than wires, then a charge carrier can become confined in all three dimensions, as illustrated in Fig. 8.3. Under certain growth conditions, when a thin layer of a semiconductor is grown on top of a substrate which has a quite different lattice constant, then in an attempt to minimize the total strain energy between the bonds, the thin layer spontaneously orders, or self-assembles into quantum dots. Microscopy has shown the dots to take the shape of pyramids, or square based 'tetrahedron' [161,162]. In the following sections example solutions will be derived for some of the simpler geometries; some of the more complex ones will have to wait until 13.

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Just as for negation, we observe that m n is a modulo-Q number for all integers m and n, but, in particular, for modulo-Q numbers ra and n. The operator is called addition modulo Q. The operators e and , together with the multiplication operator you are asked to construct in Exercise 15.27 (see below), form the basis of modular arithmetic arithmetic modulo some number Q. The exercises below ask you to establish that these three operators have some algebraic properties in common with their counterparts in normal arithmetic. Some properties of normal arithmetic do not carry over to modular arithmetic, however. One example is the subject of Exercise 15.29. The bibliographic remarks point you to practical applications of modular arithmetic. Exercise 15.27. Calculate an operator such that (mxn)modQ = (ramodQ) <8> (nmodQ) .

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Figure 8.3 A single free standing pillar containing a quantum dot and an expanded view which shows schematically the removal of all degrees of freedom for the electron momentum

for all i = 1, , 7, k 1, , K and p 1, , P; Z^ is the scaled value of the input to unit Zi for pattern p, and T is the corresponding scaled target value. Variance scaling, on the other hand, computes for each row in each matrix the standard deviations (7 deviations for matrix Z and K deviations for matrix T) over all P elements in the row. Let aZi denote the standard deviation of row i of matrix Z, and aik is the standard deviation of row k of matrix T. Then,

Exercise 15.28. Show that addition modulo Q and multiplication modulo Q are symmetric and associative. To be precise, show that, for all integers m, n and p, m e n = nera , m<8>n =

Figure 8.4 Schematic representation of the pyramidal shape of self-assembled quantum dots in highly lattice mismatched systems

and = ra<8>(n p) .

8.2 SCHRODINGER'S EQUATION IN QUANTUM WIRES The general three-dimensional Schrodinger equation for constant effective mass is:

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Mean centering and variance scaling can both be used on the same data set. Mean centering is, however, more appropriate when the data contains no biases, while variance scaling is appropriate when training data are measured with different units. Both mean centering and variance scaling can be used in situations where the minimum and maximum values are unknown. Z-score normalization is another data transformation scheme which can be used in situations where the range of values is unknown. It is essentially a combination of mean centering and variance scaling, and is very useful when there are outliers in the data. For z-score normalization,

Show, also, that negation modulo Q distributes through addition modulo Q. That is, show that, for all integers m and n, e(raen) = ( e m ) ( e n ) . (This is the hardest part of this exercise. Hint: formulate a lemma like (15.26).) Show that multiplication modulo Q distributes through addition modulo Q. That is, show that, for all integers m and n, ra (nep) = (ra n) (m p) .

In analogy to the in-plane dispersion discussed in Section 2.2, in a quantum wire it is possible to decouple the motion along the length of the wire. Taking the axis of the wire along x, then the total potential V(x, y, z) can always be written as the sum of a two-dimensional confinement potential plus the potential along the wire (which happens to be zero in this case), i.e.

Exercise 15.29 (Cancellation Properties). Show that addition of any modulo-Q number is a bijection on modulo-Q numbers. That is, show that for all modulo-Q numbers ra, n and p, ra n = m p = n = p . Show, on the contrary, that multiplication by a non-zero modulo-Q number is not necessarily a bijection on modulo-Q numbers. That is, exhibit modulo-Q numbers ra, n and p such that

The eieenfunction can then be written as a product of two components: Substituting both equation (8.4) and equation (8.5) into equation (8.3), then:

{17 o\ (<-113 )

Writing the energy as a sum of terms associated with the two components of the motion, then:

ra*0

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