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Much of the literature on scale-up of reaction systems has focused on continuous systems. However, scale-up methods for batch and semibatch operations have been included in several books, including Oldshue (1983), Whitaker and Cassano (1986) Carberry and Varma (1987) Froment and Bischoff (1990), Tatterson (1991), Harnby et al. (1992), and Baldyga and Bourne (1999). Correlations for heat transfer, mass transfer, liquid liquid dispersions, solids suspensions, and dissolution are available and are discussed in these references and in several chapters of this book. Mixing requirements for scale-up of homogeneous reactions are discussed in 13, including explanation of the limitations of the usual mixing scale-up parameter of equal power per unit volume. The reader is referred to the texts listed in the references, in which these correlations are well developed. These correlations are not reproduced in this chapter. Characterization of the physical and chemical parameters of multiphase systems with complex reactants and interfacial phenomena is extremely dif cult and may limit the usefulness of the correlations mentioned above. Achievement of a scalable microenvironment is also dif cult but may be crucial to successful scale-up. These factors, combined with the multiplicity of uses for batch reactors, argues for maximizing the versatility of both pilot and production scale equipment to encompass a range of operating conditions for speci c reactions, as well as to maximize the number of different reactions that can be run successfully. Methods of achieving this versatility are discussed in later sections and in 13. However, as wide as this range may be, there will be many reactions that cannot be scaled-up successfully without incorporation of reactor design alternatives. We discuss some of these in the next section.

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The best way to understand this measure is to see it in action. Figure 11-9 shows four sets of data artificially created to illustrate different scenarios. The two on the top have an R2 value of 0.9; the two on the bottom have an R2 value of 0.1. The two on the left have positive correlation, and the two on the right have negative correlation.

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A lattice as depicted in Figure 11.4 is a framework or structure of crossed wood or metal strips de nition from standard dictionary The Merriam-Webster Dictionary (Pocket Book) NY, 1974. A lattice is determined by a sequence of vectors b0, bi, . . . , bn21 (in real n-dimensional Rn, which are linearly independent over Zn); that is 0 u0 b0 u1 b1 un 1 b n 1 (u0 , u1 , . . . , un 1 ) [ Z n ) (u0 , b1 , . . . , bn 1) 0: The lattice L consists of all points u [ Rn, which may be written as a linear combination of the basis vectors {bi} with integer coef cients. u u 1 b 1 u2 b 2 un b n : The vectors {bi} are the basis for the lattice L. Example 11.14 The lattice in Figure 11.5 consists of all points that are integer linear combinations of the basis vectors b1 (0.125, 0.25), and b1 (20.125, 0.2). The simultaneous diophantine approximation problem is a2 a3 an , , ..., Given : a a1 a1 a1 j2 j3 jn , , ..., a UGSDA approximation to a: Find : j j1 j1 j1

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where each disjunct is a conjunctive predicate. Note that even if the global predicate is not a boolean expression of local predicates, but is satisfied by a finite number of possible global states, it can also be a disjunction of conjunctive predicates. For example, consider the rewritten predicate (z = y), where z and y are in different processes. = y ) is not a local predicate because it depends on both processes. However, if we know that and y can take values ( 0 , l ) only, we can rewrite the preceding expression follows:

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Purpose: Rounds off a numeric result to the specified number of decimal places. Syntax: Round (expression; places) where expression is a numeric expression or a field that contains a numeric value, and places is a numeric expression that indicates the number of decimal places to retain. A negative places parameter rounds to the left of the decimal point: For example, Round(1234; 2) returns 1,200. Example: The following expression returns the value of Pi to four decimals, or 3.1416.

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