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where lw is the well width and Vb is the barrier height. The previous potential definition is equivalent to a biased quantum well structure and the solutions can be found as a linear combination of Airy's functions as discussed in 2. Another important effect is that the piezoelectric field can be screened by free electrons. The linear potential causes electrons to gather close to the interfaces, therefore inducing space-charges. If the carrier density in the quantum well is comparable to the density of the piezoelectric induced charges the electrostatic field due to the free electrons can suppress the piezoelectric field. However, as the induced charge at the

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(7.10)

definition (15.24) }

Figure 7.12 On the left hand side is a schematic diagram of typical induced electric fields in a quantum well based on piezoelectric materials and on the right hand side is the band profile of a GaN/AIN quantum well structure with wavefunction moduli of the first two bound states.

Figure 7.13 Illustration of the influence of the piezoelectric field on the electronic and optical properties of GaN/AIN quantum wells, (a) the energy difference and (b) the dipole matrix element, between the first two bound states with and without the piezoelectric field.

-0 = 0 }

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where ts>max and ts,min are the new maximum and minimum values of the scaled values, linearly maps the range [t u,min, tu,max:] to the range [t s ,min, ts, max]. In the case of classification problems, target values are usually elements of the set (0.1,0.9} for the sigmoid function. The value 0.1 is used instead of 0, and 0.9 instead of 1. Since the output of the sigmoid function can only approach 0 and 1, a NN can never converge to the best set of weights if the target values are 0 or 1. In this case the goal of the NN is always out of reach, and the network continues to push weight values toward extreme values until training is stopped. Scaling of target values into a smaller range does have the disadvantage of increased training time. Engelbrecht et al. showed that if target values are linearly scaled using ts = citu+c2 (7.11)

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interfaces is usually much larger than the quantum well doping limit this screening effect is generally not pronounced in applications. The change of the band profile due to a piezoelectric field can have a strong influence on the energies of intersubband transitions. This is illustrated in Fig. 7.13(a) which shows a comparison of the transition energies between the lowest two subbands in GaN/AlGaN quantum wells with and without the internal electric field included. A substantial increase (blue shift) of the intersubband transition energies is clearly observed and has been observed experimentally [158].

Second, assume that m and n are modulo-Q numbers. Then, em = n { definition (15.24) } (-m)modQ = n { (15.19), assumption: 0 ^ n < Q } (3d :: -m = Qxd + n) = { negation (in integer arithmetic) }

The piezoelectric field can also considerably modify the localisation properties of the wavefunctions, increasing or decreasing the overlap between the ground and other excited states. This can reflect on the dipole matrix element (defined as Zij = (wi | z | Wj;)) and consequently on the intersubband optical properties of quantum well structures such as the intersubband absorption (Aij ~ |zij |2). For GaN/AlGaN quantum wells the relative change in the dipole matrix element z12 is shown in Fig. 7.13(b). Clearly, the estimated decrease of up to 50% in zij is enough to significantly deteriorate the performance of a device in a potential application. A similar problem is present in quantum well lasers based on interband transitions between the conduction and the valence bands (see [159]). The previously mentioned effects on optical transition energies and absorption strengths highlight the importance of a thorough understanding of the piezoelectric field properties for the modelling and design of optoelectronic devices.

LEARNING)

(3d :: -n = Qxd + rn) { (15.19), assumption: 0 ^ in < Q } (-n) modQ = m { definition (15.24) } en = m . We conclude that, for all modulo-Q numbers m and n,

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